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Design of oxide glass composition for laser structuring and fiber manufacturing
Thierry Cardinal  1@  , Théo Guérineau  1@  , Jean-Charles Desmoulin  1@  , Sylvain Danto  1@  , Alain Abou Khalil  2  , Yannick Petit  1@  , Yannick Ledemi  3@  , Marc Dussauze  4@  , Nadège Ollier  5@  , Lionel Canioni  2@  , Younes Messaddeq  3@  , Vincent Rodriguez  4@  , Real Vallée  3@  
1 : Institut de Chimie de la Matière Condensée de Bordeaux  (ICMCB)  -  Website
Université de Bordeaux, Institut polytechnique de Bordeaux, Centre National de la Recherche Scientifique : UMR5026
87 Avenue du Docteur Schweitzer, 33608 PESSAC cedex -  France
2 : Centre d'Études Lasers Intenses et Applications  (CELIA)  -  Website
Université de Bordeaux, Commissariat à l'énergie atomique et aux énergies alternatives : DAM/CESTA, Centre National de la Recherche Scientifique : UMR5107
351 cours de la libération 33405 Talence -  France
3 : Center of Optic, Photonic and Laser, Université Laval  (COPL)
– 2375 rue de la Terrasse, G1V 0A6 Quebec (Qc) -  Canada
4 : Institut des Sciences Moléculaires  (ISM)
Université Montesquieu - Bordeaux 4, Université Sciences et Technologies - Bordeaux 1, École Nationale Supérieure de Chimie et de Physique de Bordeaux (ENSCPB), Centre National de la Recherche Scientifique : UMR5255
Bâtiment A 12 351 cours de la Libération 33405 TALENCE CEDEX -  France
5 : Laboratoire des Solides Irradiés (LSI) – Ecole Polytechnique, Université Paris Saclay
Centre national de la recherche scientifique - CNRS (France), CEA-DRF-IRAMIS

Direct Laser Writing (DLW) using IR femtosecond laser is offering new opportunity for fabrication of advanced components and devices by mixing both top down and bottom up material processing approaches. Oxide glass are of particular interest due to their intrinsic high transparency in the visible and the near infrared range. Laser structuring allows controlling different scales at once. Indeed, the control of micro- and nano-structures for photonics using laser/material interaction is challenging and relies on the control of the local electron/hole trapping, phase separation and diffusion processes.

One of the interest of glass is the possibility of modifying and adapting the material composition. Femtosecond laser structuring applied to silver-containing tailored glass allows creating a variety of photo-induced species or nanoparticles depending on the laser parameters but also the material glass composition. Unique three-dimensional optical structures with linear and nonlinear optical properties exhibiting dimensions below the diffraction limit becomes accessible [1, 2, 3].

Pristine glass structures has an important impact on the photo-induced modifications. Introduction of rare earth in glass has been investigated in order to take advantage of the silver ions reactivity toward femtosecond laser exposure. The fabrication of photosensitive silver-containing glass fibers has been developed [4]. Correlations have been established between fiber architectures, materials chemistry and photonics properties.

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[1] G. Papon, N. Marquestaut, Y. Petit, A. Royon, M. Dussauze, V. Rodriguez, T. Cardinal, L. Canioni, Journal of Applied Physics 115, 113103 (2014).

[2] Alain Abou Khalil, Jean-Philippe Bérubé, Sylvain Danto, Jean-Charles Desmoulin, Thierry Cardinal, Yannick Petit, Real Vallee, Lionel Canioni, Scientific reports, Volume 7, Issue 1, 11124 (2017).

[3] J.-C. Desmoulin, Y. Petit, L. Canioni, M. Dussauze, M. Lahaye, H. Magallanes Gonzalez, E. Brasselet, T. Cardinal, Journal of Applied Physics 118, 213104 (2015).

[4] S. Danto, F. Désévédavy, Y. Petit , J.-C. Desmoulin, A. Abou Khalil, C. Strutynski, M. Dussauze, F. Smektala, T. Cardinal, L. Canioni, Adv. Optical Mater., 4, 162–168, (2016).



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