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Zr61Ti2Cu25Al12 bulk metallic glass: Failure under torsional loading and Mode III fracture toughness
Jian Xu  1@  , Zhen-Qiang Song, Evan Ma  2  
1 : Institute of Metal Research, Chinese Academy of Sciences  (IMR, CAS)
72 Wenhua Road -  China
2 : epartment of Materials Science and Engineering, The Johns Hopkins University
Baltimore, Maryland 21218, -  U.S. Virgin Islands

From torsional tests of cylindrical samples, we have determined the torsional properties of high-toughness Zr61Ti2Cu25Al12 (ZT1) bulk metallic glass (BMG), including its shear yield strength, ty=950 MPa, its shear elastic strain limits, gC=3.0%, and its shear modulus, G=31.5 GPa. Under torsional loading, the BMG fails via a major shear band, without obvious macroscopic plasticity on the specimen surface. The shear band maintained stable propagation by a distance of ~300 mm (~20% of cylinder radius) before final catastrophic failure, owing to the constraint of stress gradient along the radial direction. The intrinsic mode III fracture initiation toughness is measured for the Zr61Ti2Cu25Al12 BMG, which is known to have a high mode I fracture toughness (KIC). The plastic strain intensity factor GIII was used as a measure of the fracture resistance under elastic-plastic conditions. The intrinsic mode III fracture initiation toughness of ZT1 BMG, GIIIC, is found to be 29 μm, equivalent to a KIIIC of 51 MPaÖm. The corresponding fracture energy release rate is similar to or higher than that of conventional engineering metals such as high-strength aluminum alloys and some steels. The subcritical crack growth in ZT1 prior to catastrophic fracture is characterized by an extension of a microscopically zig-zag crack front. ZT1 exhibits a relatively low ratio of KIIIC/KIC of ~0.39, indicating that the material is more susceptible to mode III fracture. In engineering design with BMGs, the mode III fracture toughness is thus a useful baseline to ensure the reliability of structural components. 

 



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